Noor Zulfiqar1,*, Muhammad Asad Ali2, Faiza Rafique3, Ayesha Umar4, Urooj Umer5, Fawad Inam6,7
1Department of Chemistry, Faculty of Science, University of Agriculture, Faisalabad 38000, Pakistan.
2Department of Chemistry, Faculty of Science, Riphah International University, Faisalabad 38000, Pakistan.
3Department of Pharmacy, Imran Idrees College of Pharmacy, Sialkot 51310, Pakistan.
4Department of Pharmacy, The University of Lahore, Lahore 54000, Pakistan.
5Department of Pharmacy, Punjab University, College of Pharmacy, Lahore 54000, Pakistan.
6School of Architecture, Computing and Engineering, University of East London, Docklands Campus, London E16 2RD, UK.
7Oxford Business College, Macclesfield House, Oxford OX1 1BY, UK.
*Corresponding author:Noor Zulfiqar
References
[1] Fu F, Wang Q. Removal of heavy metal ions from wastewaters: a review. J Environ Manage. 2011;92(3):407-18.
[2] Zulfiqar N, Shariatipour M, Inam F. Sequestration of chromium(VI) and nickel(II) heavy metals from unhygienic water via sustainable and innovative magnetic nanotechnology. Nanoscale Adv. 2024;6(1):287-301.
[3] Zulfiqar N, Ali MA, Mansha N, Inam F. Policy Interventions for the Sustainable Management of Industrial and Agricultural Water Pollution in Pakistan. Int J Sustain Energy Environ. 2025;2(2):63-69.
[4] Tiwari B, et al. Review on fate and mechanism of removal of pharmaceutical pollutants from wastewater using biological approach. Bioresour Technol. 2017;224:1-12.
[5] Song X, et al. The effect of cephalexin in influencing the pharmacokinetics of a novel drug-5'-valyl-cytarabine hydrochloride. Asian J Pharm Sci. 2016.
[6] do Nascimento TG, et al. Validation of a method for determination of ampicillin in human plasma using LC-DAD. J Chromatogr Sci. 2009;47(9):749-55.
[7] Song X, et al. The effect of cephalexin in influencing the pharmacokinetics of a novel drug-5'-valyl-cytarabine hydrochloride. Asian J Pharm Sci. 2017;12(2):143-8.
[8] Pouretedal H, Sadegh N. Effective removal of amoxicillin, cephalexin, tetracycline and penicillin G from aqueous solutions using activated carbon nanoparticles prepared from vine wood. J Water Process Eng. 2014;1:64-73.
[9] Homem V, Santos L. Degradation and removal methods of antibiotics from aqueous matrices-a review. J Environ Manage. 2011;92(10):2304-47.
[10] Zulfiqar N. Effect of adding surfactant additives (sodium lauryl sulphate) in water on the performance of flat plate solar distillation system for the purification of water. 2023.
[11] Andreozzi R, Raffaele M, Nicklas P. Pharmaceuticals in STP effluents and their solar photodegradation in aquatic environment. Chemosphere. 2003;50(10):1319-30.
[12] Pérez JAS, et al. Economic evaluation of a combined photo-Fenton/MBR process using pesticides as model pollutant. Factors affecting costs. J Hazard Mater. 2013;244:195-203.
[13] Koumaki E, et al. Degradation of emerging contaminants from water under natural sunlight: The effect of season, pH, humic acids and nitrate and identification of photodegradation by-products. Chemosphere. 2015;138:675-81.
[14] Zulfiqar N. The intricacies of the chemistry of solar energy and its innovative implementations in modern technology. SSRN. 2023. Available from:
https://ssrn.com/abstract=4550873
[15] Patil PO, et al. Green fabrication of graphene-based silver nanocomposites using agro-waste for sensing of heavy metals. Res Chem Intermed. 2017;43(7):3757-73.
[16] Papageorgiou DG, Kinloch IA, Young RJ. Mechanical properties of graphene and graphene-based nanocomposites. Prog Mater Sci. 2017;90:75-127.
[17] Zulfiqar N, Arsalan M, Inam F. Heat-induced morphological changes in silver nanowires: A review. Int J Adv Nano Comput Anal. 2025;4(1):55-74.
[18] Maryami M, et al. Preparation of the Ag/RGO nanocomposite by use of Abutilon hirtum leaf extract: A recoverable catalyst for the reduction of organic dyes in aqueous medium at room temperature. Int J Hydrogen Energy. 2016;41(46):21236-45.
[19] Pandian CJ, Palanivel R, Dhananasekaran S. Green synthesis of nickel nanoparticles using Ocimum sanctum and their application in dye and pollutant adsorption. Chin J Chem Eng. 2015;23(8):1307-15.
[20] Gupta SC, et al. Neem (Azadirachta indica): An indian traditional panacea with modern molecular basis. Phytomedicine. 2017;34:14-20.
[21] Bhatt S, Chatterjee S. Fluoroquinolone antibiotics: Occurrence, mode of action, resistance, environmental detection, and remediation-A comprehensive review. Environ Pollut. 2022:120440.
[22] Du J, et al. The research status, potential hazards and toxicological mechanisms of fluoroquinolone antibiotics in the environment. Antibiotics. 2023;12(6):1058.
[23] Ma Y, et al. Efficient adsorptive removal of fluoroquinolone antibiotics from water by alkali and bimetallic salts co-hydrothermally modified sludge biochar. Environ Pollut. 2022;298:118833.
[24] Tijani JO, Fatoba OO, Petrik LF. A review of pharmaceuticals and endocrine-disrupting compounds: sources, effects, removal, and detections. Water Air Soil Pollut. 2013;224(11):1770.
[25] Ibrahim HK, et al. Validated electrochemical and chromatographic quantifications of some antibiotic residues in pharmaceutical industrial waste water. Environ Sci Pollut Res. 2017;24(8):7023-34.
[26] Kümmerer K. Antibiotics in the aquatic environment-a review-part I. Chemosphere. 2009;75(4):417-34.
[27] Elmolla ES, Chaudhuri M. Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis. Desalination. 2010;252(1):46-52.
[28] Bansal P, et al. Investigations on the degradation of an antibiotic Cephalexin using suspended and supported TiO2: Mineralization and durability studies. Can J Chem Eng. 2016;94(7):1269-76.
[29] Comninellis C, et al. Advanced oxidation processes for water treatment: advances and trends for R&D. J Chem Technol Biotechnol. 2008;83(6):769-76.
[30] Andreozzi R, et al. Advanced oxidation processes (AOP) for water purification and recovery. Catal Today. 1999;53(1):51-9.
[31] Zulfiqar N. Advanced oxidation processes for lindane degradation: A leap toward water purification excellence. SSRN. 2025. Available from:
https://ssrn.com/abstract=5355393
[32] Demirezen DA, Yıldız YŞ, Yılmaz DD. Amoxicillin degradation using green synthesized iron oxide nanoparticles: Kinetics and mechanism analysis. Environ Nanotechnol Monit Manag. 2019;11:100219.
[33] Bai X, et al. Photocatalytic degradation of some typical antibiotics: Recent advances and future outlooks. Int J Mol Sci. 2022;23(15).
[34] Balarak D, Mostafapour FK. Photocatalytic degradation of amoxicillin using UV/Synthesized NiO from pharmaceutical wastewater. In-dones J Chem. 2019;19(1):211-8.
[35] Elmolla ES, Chaudhuri M. Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis. Desalination. 2010;252(1-3):46-52.
[36] Wu Q, et al. Highly efficient photocatalytic degradation for antibiotics and mechanism insight for Bi2S3/g-C3N4 with fast interfacial charges transfer and excellent stability. Arab J Chem. 2022;15(3):103689.
[37] Sriramoju JB, et al. Magnetic photocatalytic systems. In: Sakar M, Balakrishna RG, Do TO, editors. Photocatalytic Systems by Design. Elsevier; 2021. p.503-36.
[38] Mostafaloo R, et al. Photocatalytic degradation of ciprofloxacin antibiotic from aqueous solution by BiFeO3 nanocomposites using response surface methodology. Glob J Environ Sci Manag. 2020;6(2):191-202.
[39] Malakootian M, Nasiri A, Gharaghani MA. Photocatalytic degradation of ciprofloxacin antibiotic by TiO2 nanoparticles immobilized on a glass plate. Chem Eng Commun. 2020;207(1):56-72.
[40] Zulfiqar N, Nadeem R, Musaimi OAI. Photocatalytic degradation of antibiotics via exploitation of a magnetic nanocomposite: A green nanotechnology approach toward drug-contaminated wastewater reclamation. ACS Omega. 2024.
[41] Nupearachchi C, Mahatantila K, Vithanage M. Application of graphene for decontamination of water; Implications for sorptive removal. Groundw Sustain Dev. 2017;5:206-15.
[42] Shinde Y, et al. Decoration of Pt on the metal free RGO-TiO2 composite photocatalyst for the enhanced photocatalytic hydrogen evolution and photocatalytic degradation of pharmaceutical pollutant β blocker. Int J Hydrogen Energy. 2017.
[43] Singh J, Kaur A, Saini D. A review on analysis and testing of conducting polymer and nanocomposites on the basis of their conducting properties. 2016.
[44] Velasco-Soto M, et al. Dispersion of carbon nanomaterials. In: Nanocolloids: A Meeting Point for Scientists and Technologists. Elsevier; 2016.
[45] Kharissova OV, et al. The greener synthesis of nanoparticles. Trends Biotechnol. 2013;31(4):240-8.
[46] Rodríguez-Félix F, et al. Sustainable-green synthesis of silver nanoparticles using safflower (Carthamus tinctorius L.) waste extract and its antibacterial activity. Heliyon. 2021;7(4).
[47] Moorthy SK, et al. Synthesis and characterization of MgO nanoparticles by Neem leaves through green method. Mater Today Proc. 2015;2(9):4360-8.
[48] Sohail M, et al. Modified and improved Hummer's synthesis of graphene oxide for capacitors applications. Mod Electron Mater. 2017;3(3):110-6.
[49] Van Viet P, et al. Silver nanoparticle loaded TiO2 nanotubes with high photocatalytic and antibacterial activity synthesized by photoreduction method. J Photochem Photobiol A Chem. 2018;352:106-12.
[50] Demim S, et al. Cadmium and nickel: Assessment of the physiological effects and heavy metal removal using a response surface approach by L. gibba. Ecol Eng. 2013;61:426-35.